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Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters
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dc.contributor.author |
Delaporte, Solène |
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dc.contributor.author |
Abánades Lázaro, Isabel |
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dc.contributor.author |
López Cabrelles, Javier |
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dc.contributor.author |
Mazarakioti, Eleni C. |
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dc.contributor.author |
Chebourou, Sarah |
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dc.contributor.author |
Giménez-Marqués, Mónica |
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dc.contributor.author |
Mínguez Espallargas, Guillermo |
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dc.date.accessioned |
2023-11-20T14:11:25Z |
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dc.date.available |
2023-11-20T14:11:25Z |
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dc.date.issued |
2023 |
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dc.identifier.uri |
https://hdl.handle.net/10550/91259 |
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dc.description.abstract |
A family of robust and stable molybdenum-based metal-organic cages have been obtained based on the [Mo2O2(μ2-O)2]2+ secondary building unit. The resulting cages are decorated with different pyrdine derivatives that impart structural stability, resulting in the structural elucidation of the activated cage with single-crystal diffraction. The chemical robustness of the cage is also demonstrated by the post-synthetic modification of the cage, which allows the exchange of the pyridine derivatives without rupture of the cage. |
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dc.language.iso |
eng |
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dc.relation.ispartof |
Dalton Transactions, 2023, vol. 52, p. 15682-15687 |
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dc.source |
Delaporte, Solène, Abánades Lázaro, Isabel, López Cabrelles, Javier, Mazarakioti, Eleni C., Chebourou, Sarah ,Giménez-Marqués, Mónica, Mínguez Espallargas, Guillermo (2023). Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters. Dalton Transactions 52 15682 15687. https://doi.org/10.1039/D3DT02482B |
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dc.subject |
química |
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dc.title |
Imparting structural robustness of metal-organic cages based on oxo-dimolybdenum clusters |
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dc.type |
journal article |
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dc.date.updated |
2023-11-20T14:11:25Z |
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dc.identifier.doi |
10.1039/D3DT02482B |
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dc.identifier.idgrec |
161855 |
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dc.rights.accessRights |
open access |
|
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