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Highly Luminescent Transparent Cs2AgxNa1−xBiyIn1−yCl6 Perovskite Films Produced by Single-Source Vacuum Deposition
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Stroyuk, Oleksandr; Raievska, Oleksandra; Sebastia-Luna, Paz; Huisman, Bas A. H.; Kupfer, Christian; Barabash, Anastasia; Hauch, Jens; Bolink, Henk; Brabec, Christoph J.
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This document is a artículoDate2023
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Thermal deposition of halide perovskites as a universal and scalable route to transparent thin films becomes highly challenging in the case of lead-free double perovskites, requiring the evaporation dynamics of multiple metal halide sources to be balanced or a single-phase precursor preliminary synthesized to achieve a reliable control over the composition and the phase of the final films. In the present Letter, the feasibility of the single-source vacuum deposition of microcrystalline Cs2AgxNa1-xBiyIn1-yCl6 double perovskites into corresponding transparent nanocrystalline films while preserving the bulk spectral and structural properties is shown. The perovskite films produced from the most emissive powders with x = 0.40 and y = 0.01 revealed a photoluminescence quantum yield of 85%, highlighting thermal evaporation as a promising approach to functional perovskite-based optical materials.
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