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Zero-Dimensional Hybrid Organic-Inorganic Lead Halides and Their Post-Synthesis Reversible Transformation into Three-Dimensional Perovskites

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	Huisman, Bas A. H.; Palazón Huet, Francisco; Bolink, Henk Perfil
	This document is a artículoDate2021
	Zero-dimensional (0D) mixed-halide hybrid organic-inorganic MA4PbX6·2H2O (MA = CH3NH3+; X = Br1 - xIx with 0 < x < 1) has been synthesized by a solvent-free mechanochemical approach. It has been shown that this 0D phase with sharp absorption features in the near-UV is a hydrated structure, which can be reversibly transformed into the three-dimensional perovskite phase MAPbX3 by simple thermal annealing (dehydration) in air. This work reveals a new approach to hybrid organic-inorganic perovskites and related 0D structures, which have so far only been thoroughly studied for the inorganic Cs4PbX6 compounds.
	B. A. H. Huisman, F. Palazon, H. J. Bolink Zero-Dimensional Hybrid Organic−Inorganic Lead Halides and Their Post-Synthesis Reversible Transformation into Three-Dimensional Perovskites Inorg. Chem. 60, 7, 5212–5216 (2021)
	https://doi.org/10.1021/acs.inorgchem.1c00212